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The chemical composition
and physical properties of Hydrogen Peroxide have been known for
years. It was first recognized as a chemical compound in the year
1818, although for many years thereafter it was only a laboratory
curiosity. In 1880,the first commercial production of this chemical
was undertaken in Europe. From that time the chemical process by which
it has been manufactured has undergone radical changes. Today,
Hydrogen Peroxide is being manufactured by one of two processes,
namely: the organic (Auto Oxidation "AO") process (or) by direct synthesis.
The Auto Oxidation process is the
current state of technology used world over in many plants. Research and development work on
this process dates back to the 1930's in both U.S. and Europe. The
first commercialization of this process was not undertaken until World
War II. At this time a German firm erected and operated a pilot unit
with capacity of approximately 15tons per month, They had designed and
started construction of two additional plants each having a capacity
of 15 tons per day. These were never completed.
In the AO process,
anthraquinone dissolved in an organic solvent (called working
solution) is catalytically hydrogenated to anthrahydroquinone. The
solution then passes to an oxidizer where it is contacted with air
which coverts the anthrahydroquinone to anthra quinone and hydrogen
peroxide. The hydrogen peroxide is extracted from the solution in an
extractor and can, if required, be distilled to the desired
concentration. The normal capacity for the H202 plants is between
5000 MT/year up to 50,000 MT/year. as 100% H202.
Currently developmental work is carried out for commercializing direct synthesis technology for manufacturing of hydrogen peroxide for usage in the manufacture of propylene oxide.
APL's Auto oxidation
plant is highly automated, state of art Hydrogen Peroxide plant employing
modern digital control systems. The modern control systems ensures
reliable and safe operation of the plant at optimum efficiency
and also delivering excellent product quality. Continuous upgradation
and refinement
of the process have resulted in achieving low consumption of key input chemicals and power
thus bringing down the overall cost of
production.
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